Workingbear previously wrote an article about how insufficient gold thickness in the ENIG surface treatment of a PCB led to the oxidation of Electroless Nickel, weakening solder joints and causing components detachment during plug and unplug. However, many sources explain that gold’s primary role in PCB surface finishes is to prevent nickel oxidation by acting as a barrier. Gold (Au) doesn’t strengthen solder joints and may form brittle intermetallic compounds (IMCs) like AuSn and AuSn2, leading to gold embrittlement.
Recommended reading: Two Major Potential Problems with ENIG PCB Pads (Black Nickel and Phosphorus-rich Layers) and Preventive Measures